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91.
鞠雪艳 《中国炼油与石油化工》2022,24(2):14-22
Conversion of LCO (light cycle oil) to BTX (benzene, toluene, and xylene) is an economically valuable method for refineries. However, this approach still faces difficulties as the main reactions are not clearly understood. Here we study the detailed hydrocracking pathway of typical reactants, 1-methylnaphthalene and tetralin, through molecular simulations and experiments to improve our understanding of the conversion process of LCO to BTX. Molecular simulations demonstrate that the rate-determining step is the isomerization pathway of six-membered ring to five-membered ring in tetralin as its activation energy (ΔEa) is the highest among all the reactions and the order of ΔEa of reactions is isomerization > ring-opening ≈ side-chain cleavage. The results of experiments show that with the increase in reaction depth, i.e., through a high temperature (350 – 370 °C) and low LHSV (4.5 – 6.0 h−1), isomerization, ring-opening, and side-chain cleavage reactions occurred, thus improving the selectivity and yield of alkyl aromatics. 相似文献
92.
Feng Yingrui Hu Kang Zhang Min Ding Wei Kong Xiangkai Sheng Zhigao Liu Qiangchun 《Journal of Materials Science》2022,57(1):204-216
Journal of Materials Science - Rationally designing microwave absorption materials with highly efficient and tunable bandwidth is in great demand but remains a huge challenge. In this study,... 相似文献
93.
Semiconductors - In this work, we discuss for the first time the principle of rotation in the constant electric field of a conducting particle with participation of the Lorentz force, which ensures... 相似文献
94.
Zienko S. I. Zhbanova V. L. 《Journal of Communications Technology and Electronics》2022,67(4):395-402
Journal of Communications Technology and Electronics - A quantitative comparison of the spectral characteristics of the human visual system and matrix photodetectors is carried out. Criteria for a... 相似文献
95.
Bermeshev T. V. Zhereb V. P. Bundin M. P. Yasinsky A. S. Yushkova O. V. Voroshilov D. S. Samoilo A. S. Mazurova E. V. Zaloga A. N. Yakivyuk O. V. Bespalov V. M. 《Inorganic Materials》2022,58(6):604-611
Inorganic Materials - We have studied the effect of isothermal holding of a melt containing 78 mol % Bi2O3 and 22 mol % SiO2 and various melt cooling schedules on the morphology, microstructure,... 相似文献
96.
Journal of Communications Technology and Electronics - A classification of the ambiguity of frequency determination (AFD) in a receiver with multirate sub-Nyquist sampling is proposed. It is shown... 相似文献
97.
Hu Zhaoyang Suo Xufei Shen Yongxing Jiang Yu-Xi Cheng Jun-Bo 《International Journal of Fracture》2022,235(2):231-242
International Journal of Fracture - Adiabatic shear band (ASB) is one of the most important failure modes under high strain-rate deformation. In this work, we propose a hybrid damage model to... 相似文献
98.
Measurement Techniques - To effectively minimize magnetic losses and increase the efficiency of machines, particularly transformers, exact separation of total losses in the magnetic cores of... 相似文献
99.
Geerthana M. Ramachandran K. Harish S. Ramesh R. Selvaraj M. Navaneethan M. 《Journal of Materials Science: Materials in Electronics》2022,33(12):9204-9210
Journal of Materials Science: Materials in Electronics - Herein, we report the synthesis of three-dimensional (3D) and one-dimensional (1D) hierarchical hematite (α-Fe2O3) nanostructures on... 相似文献
100.
Gayathri M. Sakar M. Satheeshkumar E. Sundaravadivel E. 《Journal of Materials Science: Materials in Electronics》2022,33(12):9347-9357
Journal of Materials Science: Materials in Electronics - Graphitic–carbon nitride (g–C3N4)-based zinc oxide (ZnO) nanocomposite (ZnO/g–C3N4) is synthesized via... 相似文献